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If you're willing to venture a little farther from home, hop a plane and rent a car, then set off to explore this American frontier.

Unlike the other Hawaiian islands, this isle's wonders aren't stacked on one coast, they're scattered along all four shorelines, right off Highway 19, which loops around the island. In other words, one road leads you everywhere you need to go, and back again—creating the perfect tropical road trip. And while geography may make the Big Island a natural do-it-yourself destination, it's the countless romantic detours—volcanoes, beaches, gardens—that turn your trip into a fairy-tale honeymoon.

Since you'll fly in and out of Kona International Airport, rent a car at the terminal and start your adventure on the Kohala-Kona Coast, which is right nearby. Some people fantasize about convertibles here, but sudden downpours—and falling coconuts—make leaving the top down a risky proposition.

Slather your arms and face with sunscreen, put on your sunglasses, and head north on Highway 19 to The Fairmont Orchid at Mauna Lani. The 540-room resort is a prime example of the Big Island's low-key luxury. Spend a day or two lounging around the pool, swinging on the golf course or winding down with a massage in an oceanfront cabana. Don't leave without trying the pistachio-chocolate soufflé at the hotel's on-site splurge, The Grill (fairmont.com).

After a couple days of rest, it's time to hit the road. Continue north on Highway 19—a road you'll come to know well—to Naalapa Stables. A wrangler will help you saddle up and a guide will lead you both into pastures of yellow tanzi flowers and through a shady forest (naalapastables.com).

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